Publications
282. |
“Enantioselective Transition-Metal Catalysis via an Anion-Binding Approach,” Ovian, J. M.; Vojáčková, P.; Jacobsen, E. N. Nature 2023, 616, 84-89. |
281. |
“Andreas Pfaltz, Inspiration and Friend,” Jacobsen, E.N. Adv. Synth. Catal. 2022, 364, 3324. |
280. |
“Evidence for Oxonium Ions in Ethereal ‘Hydrogen Chloride’,” Wagen, C. C.; Jacobsen, E.N. Organic Lett. 2022, 24, 8826-8831. |
279. |
“Exploring Structure–Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis using Data-Driven Techniques,” Mohammad, S.; Hofstra Wahlman, J.; Read, J.; Werth, J.; Jacobsen, E.N.; Sigman, M. S.; ACS Catal. 2022, 12, 14836–14845. |
278. |
“Screening for Generality in Asymmetric Catalysis,” Wagen, C. C.; McMinn, S. E.; Kwan, E. E.; Jacobsen, E.N. Nature 2022, 610, 680-686. |
277. |
“Chloride-Mediated Alkene Activation Drives Enantioselective Thiourea and Hydrogen Chloride Co-Catalyzed Prins Cyclizations,” Kutateladze, D. A.; Wagen, C. C.; Jacobsen, E.N. J. Am. Chem. Soc. 2022, 144, 15812-15824. |
276. |
“Site-Selective, Stereocontrolled Glycosylation Catalyzed by Bis-Thioureas,” Li, Q.; Levi, S. M.; Wagen, C. C.; Wendlandt, A. E; Jacobsen, E.N. Nature 2022, 608, 74-79. |
275. |
“Enantioselective hydrogen-bond-donor catalysis to access diverse stereogenic-at-P(V) compounds,” Forbes, K.A.; Jacobsen, E.N. Science 2022, 376, 1230-1236. |
274. |
“Catalytic Alkene Difunctionalization Reactions,”Ovian, J.M.; Jacobsen, E.N. in Iodine Catalysis in Organic Synthesis Ishihara, K., Muniz, K., Eds; Wiley-VCH GmbH: Weinheim, Ch.9, 243-274. |
273. |
“Chiral Ureas, Thioureas, and Squaramides in Anion-Binding Catalysis with Co-catalytic Bronsted/Lewis Acids,” Trotta, A.; Jacobsen, E.N. in Anion Binding Catalysis Garcia Mancheno, O., Eds.;Wiley-VCH GmbH: Weinheim, Ch.4, 9585-9594. |
272. |
“Cooperative Hydrogen-Bond-Donor Catalysis with Hydrogen Chloride Enables Highly Enantioselective Prins Cyclization Reactions,” Kutateladze, D.A.; Jacobsen, E.N. J. Am. Chem. Soc. 2021, 143, 20077-20083. |
271. |
“Enantioselective catalytic 1,2-boronate rearrangements,” Sharma, H.A.; Essman, J.Z.; Jacobsen, E.N. Science 2021, 374, 752-757. |
270. |
“A Case Study in Catalyst Generality: Simultaneous Highly-Enantioselective Bronsted- and Lewis-Acid Mechanisms in Hydrogen-Bond-Donor Catalyzed Oxetane Openings,” Strassfeld, D.A.; Algera, R.F.; Wickens, Z.K.; Jacobsen, E.N. J. Am. Chem. Soc. 2021, 143, 9585-9594. |
269. |
“Enantioselective, Catalytic Multicomponent Synthesis of Homoallylic Amines Enabled by Hydrogen-Bonding and Dispersive Interactions,” Ronchi, E.; Paradine, S.M.; Jacobsen, E.N. J. Am. Chem. Soc. 2021, 143, 7272-7278. |
268. |
“The Aryl-Pyrrolidine-tert-Leucine Motif as a New Privileged Chiral Scaffold: The Role of Non-Covalent Stabilizing Interactions,” Strassfeld, D.A.; Jacobsen, E.N., in Supramolecular Catalysis: New Directions and Developments, van Leeuwen, Raynal, Eds.; Wiley, New York, ISBN 978-3-527-34902-9, Chapter 25. |
267. |
“Enantioselective Aryl-Iodide-Catalyzed Wagner–Meerwein Rearrangements,”Sharma, H.A.; Mennie, K.M.; Kwan, E.E.; Jacobsen, E.N. J. Am. Chem. Soc. 2020, 142, 16090-16096. |
266. |
“Catalytic Enantioselective Synthesis of Difluorinated Alkyl Bromides,”Levin, M.D.; Ovian, J.M.; Read, J.A.; Sigman, M.S.; Jacobsen, E.N. J. Am. Chem. Soc. 2020, 142, 14831–14837. |
265. |
“Asymmetric Nazarov Cyclizations of Unactivated Dienones by Hydrogen-Bond-Donor/Lewis Acid Co-Catalyzed, Enantioselective Proton-Transfer,” Metternich, J.; Reiterer, M.; Jacobsen, E.N. Adv. Synth. Catal. 2020, 362, 4092-4097. |
264. |
“Highly Selective β-Mannosylations and β-Rhamnosylations Catalyzed by Bis-thiourea,” Li, Q.; Levi, S.M.; Jacobsen, E.N. J. Am. Chem. Soc. 2020, 142, 11865-11872. |
263. |
“Highly Enantioselective, Hydrogen-Bond-Donor Catalyzed Additions to Oxetanes,” Strassfeld, D.A.; Wickens, Z.K.; Picazo, E.; Jacobsen, E.N. J. Am. Chem. Soc. 2020, 142, 9175-9180. |
262. |
“Enantioselective Tail-to-Head Cyclizations Catalyzed by Dual-Hydrogen-Bond Donors,” Kutateladze, D.A, Strassfeld, D.A.; Jacobsen, E.N. J. Am. Chem. Soc. 2020, 142, 6951-6956. |
261. |
“Enantioselective Catalysis of an Anionic Oxy-Cope Rearrangement Enabled by Synergistic Ion Binding,” Kennedy,C.R.; Choi, B.Y.; Reeves, M.G.R.; Jacobsen, E.N. Israel J.Chem. 2020, 60, 461-474. (Special issue in honor of Stephen Buchwald and John Hartwig) |
260. |
“Stereospecific Furanosylations Catalyzed by Bis-Thiourea Hydrogen-Bond Donors,” Mayfield, A.B.; Metternich, J.B.; Trotta, A.H.; Jacobsen, E.N. J. Am. Chem. Soc. 2020, 142, 4061-4069. |
259. |
“A Catalytic One-Two Punch,” Ovian, J.M.; Jacobsen, E.N. Science 2019, 366, 948-949 (Perspective). |
258. |
“Catalyst-Controlled Glycosylations,” Levi, S.M.; Jacobsen, E.N. Organic Reactions 2019, 100, 801-852. |
257. |
“Enantioselective Synthesis of α-Allyl Amino Esters via Hydrogen-Bond Donor Catalysis,” Bendelsmith, A.J.; Kim, S.C.; Wasa, M.; Roche, S.P.; Jacobsen, E.N. J. Am. Chem. Soc. 2019, 141, 11414-11419. |
256. |
“Catalytic, Enantioselective 1,2 Difluorination of Cinnamamides,” Haj, .K.; Banik, S.M.; Jacobsen, E.N. Org. Lett. 2019, 21, 4919-4923. |
255. |
“Catalytic Activation of Glycosyl Phosphates for Stereoselective Coupling Reactions,” Levi, S.M.; Li, Q.; Roetheli, A.R.; Jacobsen, E.N. Proc. Natl. Acad. Sci. USA 2019, 116, 35-39. |
254. |
“Mechanism and Origins of Chemo-and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes,” Zhou, B.; Haj, M.K.; Jacobsen, E.N.; Houk, K.N.; Xue, X.S. J. Am. Chem. Soc. 2018, 140, 15206-15218. |
253. |
“Concerted nucleophilic aromatic substitutions,” Kwan, E.E.; Zeng, Y.; Besser, H.A.; Jacobsen, E.N. Nature Chem. 2018,10 , 917-923. |
252. |
“Quaternary Stereocenters via an Enantioconvergent Catalytic SN1 Reaction,” Wendlandt, A.E.; Vangal, P.; Jacobsen, E.N. Nature 2018, 556 , 447-451. |
251. |
“Catalytic Diastereo-and Enantioselective Fluoroamination of Alkenes,” Mennie, K.M., Banik, S.M.; Reichert, E.C., Jacobsen, E.N. J.Am.Chem.Soc. 2018, 140 , 4797-4802. |
250. |
“Lewis Acid Enhancement by Hydrogen-Bond Donors for Asymmetric Catalysis,” Banik, S.M.; Levina, A.; Hyde, A. M.; Jacobsen, E.N. Science 2017, 358 , 761-764. |
249. |
“Chiral Thioureas Promote Enantioselective Pictet–Spengler Cyclization by Stabilizing Every Intermediate and Transition State in the Carboxylic Acid-Catalyzed Reaction,” Klausen, R. S.; Kennedy, C. R.; Hyde, A. M.; Jacobsen, E.N J. Am. Chem. Soc. 2017, 139 , 12299-12309. |
248. |
“Catalytic 1,3-Difunctionalization via Oxidative C–C Bond Activation,” Banik, S.M.; Mennie, K.; Jacobsen, E.N. J. Am. Chem. Soc. 2017, 139, 9152-9155. |
247. |
“Sensitive and Accurate 13C Kinetic Isotope Effect Measurements Enabled by Polarization Transfer,” Kwan, E.E.; Park, Y.; Besser, H.A.; Anderson, T.L.; Jacobsen, E.N. J. Am. Chem. Soc. 2017, 139 (1) , 43-46. |
246. |
“Macrocyclic Bis-Thioureas Catalyze Stereospecific Glycosylation Reactions,” Park, Y.; Harper, K.C.; Kuhl, N.; Kwan, E.E.; Liu, R.Y.; Jacobsen, E.N. Science 2017, Vol. 355, Issue 6321, 162-166. |
245. |
“Enantioselective Aza-Sakurai Cyclizations: Dual Role of Thiourea as H-bond Donor and Lewis Base,” Park, Y.; Schindler, C.S.; Jacobsen, E.N. J. Am. Chem. Soc. 2016, 138, 14848-14851. |
244. |
“Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source,” Woerly, E.M.; Banik, S.M.; Jacobsen, E.N. J. Am. Chem. Soc. 2016, 138, 13858-13861. |
243. |
“Mechanism-Guided Development of a Highly Active, Dimeric Thiourea Catalyst for Anion-Abstraction Catalysis,” Kennedy, C.R.; Lehnherr, D.; Rajapaksa, N.S.; Ford, D.D.; Park, Y.; Jacobsen, E.N. J. Am. Chem. Soc. 2016, 138, 13525-13528. |
242. |
“Conformational Control of Chiral Amido-Thiourea Catalysts Enables Improved Activity and Enantioselectivity,” Lehnherr, D.; Ford, D.D.; Bendelsmith, A.; Kennedy, C.R.; Jacobsen, E.N. Org. Lett. 2016, 18, 3214-3217. |
241. |
“Anion-Abstraction Catalysis: The Cooperative Mechanism of α-Chloroether Activation by Dual H-Bond Donors,” Ford, D.D.; Lehnherr, D.; Kennedy, C.R.; Jacobsen, E.N. ACS Catal. 2016, 6, 4616-4620. |
240. |
“On-and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis,” Ford, D.D.; Lehnherr, D.; Kennedy, C.R.; Jacobsen, E.N. J. Am. Chem. Soc. 2016, 138, 7860-7863. |
239. |
“Organometallic Chemistry: A New Metathesis,” Hennessy, E.T.; Jacobsen, E.N. Nature Chem. 2016, 8, 741-742. |
238. |
“Catalytic Asymmetric Difluorination of Alkenes to Generate Difluoromethylated Stereocenters,” Banik, S.M.; Medley, J.W.; Jacobsen, E.N. Science 2016, 353, 51-54. |
237. |
“Synergistic Ion-Binding Catalysis Demonstrated via an Enantioselective, Catalytic [2,3]-Wittig Rearrangement, ” Kennedy, C.R.; Guidera, J.A.; Jacobsen, E.N. ACS Cent. Sci. 2016, 2, 416-423. |
236. |
“Catalytic, Diastereoselective 1,2-Difluorination of Alkenes,” Banik, S.M.; Medley, J.W.; Jacobsen, E. N. J. Am. Chem. Soc. 2016, 138,5000-5003. |
235. |
“The cation-π Interaction in Small-Molecule Catalysis” Kennedy, C.R.; Lin, S.; Jacobsen, E. N. Angew. Chem. Int. Ed. ,in press. doi: 10.1002/anie.201600547R1(Review) |
234. |
“Activation of Electron-Deficient Quinones through Hydrogen-Bond-Donor-Coupled Electron Transfer,” Turek, A.K.; Hardee, D.M.; Ullman, A.; Nocera, D.C.; Jacobsen, E. N. Angew. Chem. Ed. 2016, 55,539-544 [Angew. Chem. 2016128,549-554] |
233. |
“A Simple Primary Amine Catalyst for Enantioselective α-Hydroxylations and α-Fluorinations of Branched Aldehydes,” Witten, M.R.; Jacobsen, E. N. Organic Lett. |
232. |
“Enantioselective synthesis of tertiary α-chloro esters by non-covalent catalysis,” Liu, R.Y.; Wasa, M.; Jacobsen, E. N. Tetrahedron Lett. 2015, 56,3428-3430 (Special issue honoring Harry Wasserman) |
231. |
“Highly Enantioselective, Intermolecular Hydroamination of Allenyl Esters Catalyzed by Bifunctional Phosphinothioureas,” Fang, Y.-Q.; Tadross, P.M.; Jacobsen, E.N. J. Am. Chem. Soc. 2014, 136, 17966-17968 [Supporting Information] |
230. |
“Enantioselective Selenocyclization via Dynamic Kinetic Resolution of Seleniranium Ions by Hydrogen-Bond Donor Catalysts” Zhang, H.; Lin, S.; Jacobsen, E. N. J. Am. Chem. Soc. 2014, 136, 16485-16488 [Supporting Information] |
229. |
Jacobsen, E. N.; Zuend, S. J. "Compound reagents and method for synthesizing enantiomerically enriched amino acids," U.S. Patent #8859812, October 14, 2014. |
228. |
“Thiourea-Catalyzed Enantioselective Addition of Indoles to Pyrones: Alkaloid Cores with Quaternary Carbons” Yeung, C. S.; Ziegler, R. E.; Porco, J. A., Jr.; Jacobsen, E. N. J. Am. Chem. Soc. 2014, 136, 13614-13617 [Supporting Information] |
227. |
“Asymmetric Mannich Synthesis of α-Amino esters by Anion-Binding Catalysis” Wasa, M,; Liu, R. Y.; Roche, S. P.; Jacobsen, E. N. J. Am. Chem. Soc. 2014, 136, 12872-12875 [Supporting Information] |
226. |
“Chiral sulfinamidourea and strong Brønsted acid–cocatalyzed enantioselective Povarov reaction to access tetrahydroquinolines” Xu, H.; Zhang, H.; Jacobsen, E. N. Nat. Protoc. 2014, 9, 1860-1866. |
225. |
“Catalytic Asymmetric Synthesis of 8-Oxabicyclooctanes by Intermolecular [5+2] Pyrylium Cycloadditions” Witten, M. R.; Jacobsen, E. N. Angew. Chem. Int. Ed. 2014, 53, 5912-5916. [Supporting Information] |
224. |
“A broadly applicable and practical oligomeric salen(Co) catalyst for enantioselective epoxide ring-opening reactions,” White, D. E.; Tadross, P. M.; Lu, Z.; Jacobsen, E. N. Tetrahedron 2014, 70, 4165-4180. |
223. |
“Photoredox Activation and Anion-Binding in the Dual Catalytic Enantioselective Synthesis of β-Amino Esters” Bergonzini, G.; Schindler, C. S.; Wallentin, C.-J.; Jacobsen, E. N.; Stephenson, C. R. J. Chem. Sci. 2014, 5, 112-116. [Supporting Information] |
222. |
“Mechanistic Basis for High Selectivity and Broad Substrate Scope in the (salen)Co(III)-Catalyzed Hydrolytic Kinetic Resolution” Ford, D. D.; Nielsen, L. P. C.; Zuend, S. J.; Musgrave, C. B.; Jacobsen, E. N. J. Am. Chem. Soc. 2013,135, 15595-15608. [Supporting Information] |
221. |
“Enantioselective Catalytic Transannular Ketone Ene Reactions” Rajapaksa, N.S.; Jacobsen, E. N. Org. Lett. 2013, 15, 4238–4241. [Supporting Information] |
220. |
“A Practical Method for the Synthesis of Highly Enantioenriched trans-1,2-Amino Alcohols” Birrell, J. A.; Jacobsen, E. N. Org. Lett. 2013, 15, 2895–2897. [Supporting Information] |
219. |
“A New Twist on Cooperative Catalysis” Schindler, C. S.; Jacobsen, E. N. Science 2013, 340, 1052–1053 (Perspective). |
218. |
“Enantioselective Thiourea-Catalyzed Intramolecular Cope-Type Hydroamination” Brown, A. R.; Uyeda, C.; Brotherton, C. A.; Jacobsen, E. N. J. Am. Chem. Soc. 2013, 135, 6747–6749. [Supporting Information] |
217. |
“Chiral β-Iodoamines by Urea-Catalysed Iodocyclization of Trichloroacetimidates” Brindle, C. S.; Yeung, C. S.; Jacobsen, E. N. Chem. Sci. 2013, 4, 2100–2104. [Supporting Information] |
216. |
“Enantioselective Formal Aza-Diels–Alder Reactions of Enones with Cyclic Imines Catalyzed by Primary Aminothioureas” Lalonde, M. P.; McGowan, M. A.; Rajapaksa, N. S.; Jacobsen, E. N. J. Am. Chem. Soc. 2013, 135, 1891–1894. [Supporting Information] |
215. |
“Enantioselective Total Synthesis of (+)-Reserpine” Rajapaksa, N. S.; McGowan, M. A.; Rienzo, M.; Jacobsen, E. N. Org. Lett. 2013, 15, 706–709. [Supporting Information] |
214. |
“Asymmetric Ion-Pairing Catalysis” Brak, K.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2013, 52, 534–561. |
213. |
“Remodelling by diversity and design” Tadross, P. M.; Jacobsen, E. N. Nature Chem. 2012, 4, 963–965 (News & Views). |
212. |
“Application of a Catalytic Asymmetric Povarov Reaction using Chiral Ureas to the Synthesis of a Tetrahyroquinoline Library” Gerard, B; O’Shea, M. W.; Donckele, E.; Kesavan, S.; Akella, L. B.; Xu, H.; Jacobsen, E. N.; Marcaurelle, L. A. ACS Comb. Sci. 2012, 14, 621–630. [Supporting Information] |
211. |
“Thiourea-catalysed ring opening of episulfonium ions with indole derivatives by means of stabilising, non-covalent interactions” Lin, S.; Jacobsen, E. N. Nature Chem. 2012, 4, 817–824. [Supporting Information] |
210. |
“Catalysis in Tight Spaces” Burns, N. Z.; Jacobsen, E. N. Nature 2012, 483, 278–279 (News & Views). |
209. |
“Mechanistic Basis for High Reactivity of (salen)Co-OTs in the Hydrolytic Kinetic Resolution of Terminal Epoxides” Nielsen, L. P. C.; Zuend, S. J.; Ford, D. D.; Jacobsen, E. N. J. Org. Chem. 2012, 77, 2486–2495. [Supporting Information] |
208. |
"Thiourea-Catalyzed Enantioselective Iso-Pictet–Spengler Reactions” Lee, Y.; Klausen, R. S.; Jacobsen, E. N. Org. Lett. 2011, 13, 5564–5567. [Supporting Information] |
207. |
"Dual Catalysis in Enantioselective Oxidopyrylium-Based [5 + 2] Cycloadditions” Burns, N. Z.; Witten, M. R.; Jacobsen, E. N. J. Am. Chem. Soc. 2011, 133, 14578–14581. [Supporting Information] |
206. |
"Enantioselective Acylation of Silyl Ketene Acetals through Fluoride Anion-Binding Catalysis" Birrell, J. A.; Desrosiers, J.-N.; Jacobsen, E. N. J. Am. Chem. Soc. 2011, 133, 13872–13875. [Supporting Information] |
205. |
"Chiral Sulfinamide/Achiral Sulfonic Acid Cocatalyzed Enantioselective Protonation of Enol Silanes" Beck, E. M.; Hyde A. M.; Jacobsen E. N. Org. Lett. 2011, 13, 4260–4263. [Supporting Information] |
204. |
"Transition State Charge Stabilization Through Multiple Non-Covalent Interactions in the Guanidinium-Catalyzed Enantioselective Claisen Rearrangement" Uyeda, C.; Jacobsen, E. N. J. Am. Chem. Soc. 2011, 133, 5062–5075. [Supporting Information] |
203. |
"Catalytic Enantioselective Claisen Rearrangements of O-Allyl β-Ketoesters" Uyeda, C.; Rötheli, A. R.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2010, 49, 9753–9756. [Supporting Information] |
202. |
Burns, N. Z.; Jacobsen, E. N. Mannich Reaction. In Stereoselective Synthesis 2: Stereoselective Reactions of Carbonyl and Imino Groups; Molander, G., Ed.; Georg Thieme Verlag: New York, 2010; Chapter 2.16. |
201. |
"Organocatalysis" Jacobsen, E. N.; MacMillan, D. W. C. Proc. Natl. Acad. Sci. USA 2010, 107, 20618–20619. |
200. |
"Attractive Non-Covalent Interactions in Asymmetric Catalysis: Links Between Enzymes and Small-Molecule Catalysts" Knowles, R. R.; Jacobsen, E. N. Proc. Natl. Acad. Sci. USA 2010, 107, 20678–20685. |
199. |
"Tertiary Aminourea-Catalyzed Enantioselective Iodolactonization" Veitch, G. E.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2010, 49, 7332–7335. [Supporting Information] |
198. |
"Enantioselective Catalytic α-Alkylation of Aldehydes via an SN1 Pathway" Brown, A. R.; Kuo, H.-S.; Jacobsen, E. N. J. Am. Chem. Soc. 2010, 132, 9286–9288. [Supporting Information] |
197. |
"An Enantioselective Total Synthesis of (+)-Peloruside A" McGowan, M. A.; Stevenson, C. P.; Schiffler, M. A.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2010, 49, 6147–6150. [Supporting Information] |
196. |
"Enantioselective Thiourea-Catalyzed Cationic Polycyclizations” Knowles, R. R.; Lin, S.; Jacobsen, E. N. J. Am. Chem. Soc. 2010, 132, 5030–5032. [Supporting Information] |
195. |
"Asymmetric Cooperative Catalysis of Strong Brønsted Acid-Promoted Reactions Using Chiral Ureas” Xu, H.; Zuend, S. J.; Woll, M. P.; Tao, Y.; Jacobsen, E. N. Science 2010, 327, 986–990. [Supporting Information] |
194. |
"Mechanism of Amido-Thiourea Catalyzed Enantioselective Imine Hydrocyanation: Transition State Stabilization via Multiple Non-Covalent Interactions" Zuend, S. J., Jacobsen, E. N. J. Am. Chem. Soc. 2009, 131, 15358–15374. [Supporting Information] |
193. |
"Scaleable catalytic asymmetric Strecker syntheses of unnatural α-amino acids" Zuend, S. J.; Coughlin, M. P.; Lalonde, M. P.; Jacobsen, E. N. Nature 2009, 461, 968–970. [Supporting Information] |
192. |
"Enantioselective, Thiourea-Catalyzed Intermolecular Addition of Indoles to Cyclic N-Acyl Iminium Ions" Peterson, E. A.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2009, 48, 6328–6331. [Supporting Information] |
191. |
"Bifunctional Asymmetric Catalysis with Hydrogen Chloride: Enantioselective Ring Opening of Aziridines Catalyzed by a Phosphinothiourea" Mita, T.; Jacobsen, E. N. Synlett 2009, 1680–1684 (Special Cluster Issue on Cooperative Catalysis). |
190. |
"Enantioselective Intramolecular Openings of Oxetanes Catalyzed by (salen)Co(III) Complexes: Access to Enantioenriched Tetrahydrofurans" Loy, Rebecca N.; Jacobsen, E. N. J. Am. Chem. Soc. 2009, 131, 2786–2787. [Supporting Information] |
189. |
"Weak Brønsted Acid-Thiourea Co-catalysis: Enantioselective, Catalytic Protio-Pictet–Spengler Reactions" Klausen, R. S.; Jacobsen, E. N. Org. Lett. 2009, 11, 887–890. [Supporting Information] |
188. |
"Structural Analysis of Spiro β-Lactone Proteasome Inhibitors" Groll, M.; Balskus, E. P.; Jacobsen, E. N. J. Am. Chem. Soc. 2008, 130, 14981–14983. [Supporting Information] |
187. |
"Asymmetric Intramolecular Arylcyanation of Unactivated Olefins via C–CN Bond Activation” Watson, M. P.; Jacobsen, E. N. J. Am. Chem. Soc. 2008, 130, 12594–12595. [Supporting Information] |
186. |
"Enantioselective Claisen Rearrangements with a Hydrogen-Bond Donor Catalyst" Uyeda, C.; Jacobsen, E. N. J. Am. Chem. Soc. 2008, 130, 9228–9229. [Supporting Information] |
185. |
"Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions" Reisman, S. E.; Doyle, A. G.; Jacobsen, E. N. J. Am. Chem. Soc. 2008, 130, 7198–7199. [Supporting Information] |
184. |
"Cooperative, Highly Enantioselective Phosphinothiourea Catalysis of Imine-Allene [3+2] Cycloadditions" Fang, Y.-Q.; Jacobsen, E. N. J. Am. Chem. Soc. 2008, 130, 5660–5661. [Supporting Information] |
183. |
"Regio- and Enantioselective Cyclization of Pyrroles onto N-Acyliminium Ions" Raheem, I. T.; Thiara, P. V.; Jacobsen, E. N. Org. Lett. 2008, 10, 1577–1580. [Supporting Information] |
182. |
"Cooperative Catalysis in the Hydrolytic Kinetic Resolution of Epoxides by Chiral [(salen)CoIII] Complexes Immobilized on Gold Colloids" Belser, T.; Jacobsen, E. N. Adv. Synth. Catal. 2008, 350, 967–971. |
181. |
"Catalytic Asymmetric Total Synthesis of (+)-Yohimbine" Mergott, D. J.; Zuend, S. J.; Jacobsen, E. N. Org. Lett. 2008, 10, 745–748. [Supporting Information] |
180. |
"Dimeric (salen)Al Complexes Display Expanded Scope in the Conjugate Cyanation of a β-Unsaturated Imides" Mazet, C.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2008, 47, 1762–1765. [Supporting Information] |
179. |
"Enantioselective Catalytic Carbonyl-ene Cyclization Reactions" Grachan, M. L.; Tudge, M. T.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2008, 47, 1469–1472. [Supporting Information] |
178. |
"Small-Molecule H-Bond Donors in Asymmetric Catalysis" Doyle, A. G.; Jacobsen, E. N. Chem. Rev. 2007, 107, 5713–5743. |
177. |
"Cooperative Catalysis by Tertiary Amino-Thioureas: Mechanism and Basis for Enantioselectivity of Ketone Cyanosilylation" Zuend, S. J.; Jacobsen, E. N. J. Am. Chem. Soc. 2007, 129, 15872–15883. [Supporting Information] |
176. |
"Enantioselective Pictet–Spengler-Type Cyclizations of Hydroxylactams: H-Bond Donor Catalysis by Anion Binding" Raheem, I. T.; Thiara, P. V.; Peterson, E. A.; Jacobsen, E. N. J. Am. Chem. Soc. 2007, 129, 13404–13405. [Supporting Information] |
175. |
"Asymmetric Catalysis of the Transannular Diels–Alder Reaction" Balskus, E. P.; Jacobsen, E. N. Science 2007, 317, 1736–1740. [Supporting Information] |
174. |
"Enantioselective Alkylation of Acyclic α,α-Disubstituted Tributyltin Enolates Catalyzed by a {Cr(salen)} Complex" Doyle, A. G.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2007, 46, 3701–3705. [Supporting Information] |
173. |
"Indium-Mediated Asymmetric Allylation of Acylhydrazones Using a Chiral Urea Catalyst" Tan, K. L.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2007, 46, 1315–1317. [Supporting Information] |
172. |
"Alk-2-enoic Acid Esters” Vanderwal, C. D.; Jacobsen, E. N. Science of Synthesis 2006, 20b, 1305–1340. |
171. |
"Arenecarboxylic Acid Esters" Yoon, T. P.; Jacobsen, E. N. Science of Synthesis 2006, 20b, 1285–1304. |
170. |
"Alk-2-enoic Acids" Vanderwal, C. D.; Jacobsen, E. N. Science of Synthesis 2006, 20a, 551–568. |
169. |
"Arenecarboxylic Acids" Yoon, T. P.; Jacobsen, E. N. Science of Synthesis 2006, 20a, 533–549. |
168. |
"Preparation of (S)-Methyl Glycidate via Hydrolytic Kinetic Resolution" Stevenson, C. P.; Nielsen, L. P. C. Jacobsen, E. N. Org. Synth. 2006, 83, 162–166. |
167. |
"A Chiral Primary Amine-Thiourea Catalyst for the Highly Enantioselective Direct Conjugate Addition of α,α-Disubstituted Aldehydes to Nitroalkenes" Lalonde, M. P.; Chen, Y.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2006, 45, 6366–6370. [Supporting Information] |
166. |
"Highly Enantioselective Direct Conjugate Addition of Ketones to Nitroalkenes Promoted by A Chiral Primary Amine-Thiourea Catalyst" Huang, H.; Jacobsen, E. N. J. Am. Chem. Soc. 2006, 128, 7170–7171. [Supporting Information] |
165. |
"α,β-Unsaturated β-Silyl Imide Substrates for Catalytic, Enantioselective Conjugate Additions: A Total Synthesis of (+)-Lactacystin and the Discovery of a New Proteasome Inhibitor" Balskus, E. P.; Jacobsen, E. N. J. Am. Chem. Soc. 2006, 128, 6810–6812. [Supporting Information] |
164. |
"Asymmetric Catalysis by Chiral Hydrogen Bond Donors" Taylor, M. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2006, 45, 1520–1543. |
163. |
Nielsen, L. P. C. Jacobsen, E. N. Catalytic, Asymmetric Epoxide Ring-Opening Chemistry. In Aziridines and Epoxides in Organic Synthesis; Yudin, A., Ed.; Wiley: New York, 2006; Chapter 10. |
162. |
"An Efficient, Highly Diastereo- and Enantioselective Hetero-Diels-Alder Catalyst. Preparation of (2S,6R)-6-(tert-Butyldimethylsilyloxymethyl)-2-Methoxy-2,5-Dihydropyran" Chavez, D. E.; Jacobsen, E. N. Org. Synth. 2005, 82, 34–42. |
161. |
"Highly Enantioselective Aza-Baylis–Hillman Reactions Catalyzed by Chiral Thiourea Derivatives" Raheem, I. T.; Jacobsen, E. N. Adv. Synth. Catal. 2005, 347, 1701–1708. [Supporting Information] |
160. |
"Enantioselective Thiourea-Catalyzed Acyl-Mannich Reactions of Isoquinolines" Taylor, M. S.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2005, 44, 6700–6704. [Supporting Information] |
159. |
"Efficient Total Syntheses of (–)-Colombiasin A and (–)-Elisapterosin B: Application of the Cr-Catalyzed Asymmetric Quinone Diels–Alder Reaction" Boezio, A. A.; Jarvo, E. R.; Lawrence, B. M.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2005, 44, 6046–6050. [Supporting Information] |
158. |
"Highly Enantio- and Regioselective Quinone Diels–Alder Reactions Catalyzed by a Tridentate (Schiff Base)Cr(III) Complex" Jarvo, E. R.; Lawrence, B. M.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2005, 44, 6043–6046. [Supporting Information] |
157. |
"Thiourea-Catalyzed Enantioselective Cyanosilylation of Ketones" Fuerst, D. E.; Jacobsen, E. N. J. Am. Chem. Soc. 2005, 127, 8964–8965. [Supporting Information] |
156. |
Wenzel, A. G.; Jacobsen, E. N. Asymmetric Catalysis in the Enantioselective Synthesis of β-Amino Acids. In Enantioselective Synthesis of beta-Amino Acids; Juaristi, E., Soloshonok, V., Eds.; Wiley-VCH: New York, 2005; Chapter 4. |
155. |
"Highly Enantioselective Catalytic Conjugate Addition of N-Heterocycles to α,β-Unsaturated Ketones and Imides" Gandelman, M.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2005, 44, 2393–2397. [Supporting Information] |
154. |
"Highly Enantioselective Conjugate Additions to α,β-Unsaturated Ketones Catalyzed by a (salen)Al Complex" Taylor, M. S.; Zalatan, D. N.; Lerchner, A. M.; Jacobsen, E. N. J. Am. Chem. Soc. 2005, 127, 1313–1317. [Supporting Information] |
153. |
Jacobsen, E. N.; Sigman, M. S. Main Group Metal-Based Asymmetric Catalysts and Applications Thereof. U.S. Patent #6844448, January 18, 2005. |
152. |
"Highly Enantioselective Thiourea-catalyzed Nitro-Mannich Reaction" Yoon, T. P.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2005, 44, 466–468. [Supporting Information] |
151. |
"Enantioselective Alkylations of Tributyltin Enolates Catalyzed by Cr(salen)Cl: Access to Enantiomerically Enriched All Carbon Quaternary Centers" Doyle, A. G.; Jacobsen, E. N. J. Am. Chem. Soc. 2005, 127, 62–63. [Supporting Information] |
150. |
Jacobsen, E. N.; Tokunaga, M.; Larrow, J. F. Hydrolytic Kinetic Resolution of Cyclic Substrates. U.S. Patent #6800766, October 5, 2004. |
149. |
"Highly Enantioselective Hydration of α,β-Unsaturated Imides by Al-Catalyzed Conjugate Addition of Oxime Nucleophiles" Vanderwal, C. D.; Jacobsen, E. N. J. Am. Chem. Soc. 2004, 126, 14724–14725. [Supporting Information] |
148. |
"Highly Enantioselective Catalytic Acyl-Pictet–Spengler Reactions" Taylor, M. S.; Jacobsen, E. N. J. Am. Chem. Soc. 2004, 126, 10558–10559. [Supporting Information] |
147. |
"Cooperative Dual Catalysis: Application to the Highly Enantioselective Conjugate Cyanation of Unsaturated Imides" Sammis, G. M.; Danjo, H.; Jacobsen, E. N. J. Am. Chem. Soc. 2004, 126, 9928–9929. [Supporting Information] |
146. |
"General Catalytic Synthesis of Highly Enantiomerically Enriched Terminal Aziridines from Racemic Epoxides" Kim, S.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2004, 43, 3952–3954. [Supporting Information] |
145. |
"Asymmetric Processes Catalyzed by Chiral (Salen)Metal Complexes” Larrow, J. F.; Jacobsen, E. N. Top. Organomet. Chem. 2004, 6, 123–152. |
144. |
Jacobsen, E. N.; Sigman, M. S. Parallel Combinatorial Approach to the Discovery and Optimization of Catalysts and Uses Thereof. U.S. Patent #6709824 B2, March 23, 2004. |
143. |
"Asymmetric Catalysis in Complex Target Synthesis" Taylor, M. S.; Jacobsen, E. N. Proc. Nat. Acad. Sci. USA 2004, 101, 5368–5373. |
142. |
"Thiourea-Catalyzed Enantioselective Hydrophosphonylation of Imines: Practical Access to Enantiomerically Enriched α-Amino Phosphonic Acids" Joly, G. D.; Jacobsen, E. N. J. Am. Chem. Soc. 2004, 126, 4102–4103. [Supporting Information] |
141. |
Liu, Y.; DiMare, M.; Marchese, S. A.; Jacobsen, E. N.; Jasmin, S. Hydrolytic Kinetic Resolution of Epoxides. U.S. Patent #6693206, February 17, 2004. |
140. |
"Mechanistic Investigation Leads to a Synthetic Improvement in the Hydrolytic Kinetic Resolution of Terminal Epoxides" Nielsen, L. C. P.; Stevenson, C. P.; Blackmond, D.G.; Jacobsen, E. N. J. Am. Chem. Soc. 2004, 126, 1360–1362. [Supporting Information] |
139. |
"Catalytic Asymmetric Total Syntheses of Quinine and Quinidine" Raheem, I. T.; Goodman, S. N.; Jacobsen, E. N. J. Am. Chem. Soc. 2004, 126, 706–707. [Supporting Information] |
138. |
"Asymmetric Hydrocyanation of Hydrazones Catalyzed by Lanthanide - PYBOX Complexes” Keith, J. M.; Jacobsen, E. N. Org. Lett. 2004, 6, 153–155. [Supporting Information] |
137. |
Vachal, P.; Jacobsen, E. N. Cyanation of Carbonyl and Imino Groups. In Comprehensive Asymmetric Catalysis (1st Supplement); Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 2003; Chapter 28. |
136. |
"New Oligomeric Catalyst for the Hydrolytic Kinetic Resolution of Terminal Epoxides Under Solvent-Free Conditions" White, D. E.; Jacobsen, E. N. Tetrahedron: Asymm. 2003, 14, 3633–3638. |
135. |
"Asymmetric Hetero-Ene Reactions of Trimethylsilyl Enol Ethers Catalyzed by Tridentate Schiff Base Chromium(III) Complexes" Ruck, R. T.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2003, 42, 4771–4774. [Supporting Information] |
134. |
"Divergent Stereoinduction Mechanisms in Urea-Catalyzed Additions to Imines" Wenzel, A. G.; Lalonde, M. P.; Jacobsen, E. N. Synlett 2003, 12, 1919–1922. |
133. |
"Enantioselective Michael Additions to α,β-Unsaturated Imides Catalyzed by a Salen-Al Complex" Taylor, M. S.; Jacobsen, E. N. J. Am. Chem. Soc. 2003, 125, 11204–11205. [Supporting Information] |
132. |
"Catalyst-Controlled Inverse Electron Demand Hetero-Diels–Alder Reactions in the Enantio- and Diastereoselective Synthesis of Iridoid Natural Products" Chavez, D. E.; Jacobsen, E. N. Org. Lett. 2003, 5, 2563–2565. [Supporting Information] |
131. |
Jacobsen, E. N.; Sigman, M. S. Main Group Metal-Based Asymmetric Catalysts and Applications Thereof. U.S. Patent #6521561, February 18, 2003. |
130. |
"Highly Enantioselective, Catalytic Conjugate Addition of Cyanide to α,β-Unsaturated Imides" Sammis, G. M.; Jacobsen, E. N. J. Am. Chem. Soc. 2003, 125, 4442–4443. [Supporting Information] |
129. |
"Privileged Chiral Catalysts" Yoon, T. P.; Jacobsen, E. N. Science 2003, 299, 1691–1693. |
128. |
"Enantiopure β-Hydroxy Morpholine Amides From Terminal Epoxides via Carbonylation at 1 Atm” Goodman, S. N.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2002, 41, 4703–4705. [Supporting Information] |
127. |
"The Simplest 'Enzyme'" Movassaghi, M.; Jacobsen, E. N. Science 2002, 298, 1904–1905 (Perspective). |
126. |
"Asymmetric Catalytic Mannich Reactions Catalyzed by Urea Derivatives: Enantioselective Synthesis of β-Aryl-β-Amino Acids" Wenzel, A. G.; Jacobsen, E. N. J. Am. Chem. Soc. 2002, 124, 12964–12965. [Supporting Information] |
125. |
"A Practical Synthesis of α,β-Unsaturated Imides, Useful Substrates For Asymmetric Conjugate Addition Reactions" Goodman, S. N.; Jacobsen, E. N. Adv. Synth. Catal. 2002, 344, 953–956. |
124. |
Jacobsen, E. N.; Tokunaga, M.; Larrow, J. F. Hydrolytic Kinetic Resolution of Cyclic Substrates. U.S. Patent #6448414, September 10, 2002. |
123. |
"Structure-Based Analysis and Optimization of a Highly Enantioselective Catalyst for the Strecker Reaction" Vachal, P.; Jacobsen, E. N. J. Am. Chem. Soc. 2002, 124, 10012–10014. [Supporting Information] |
122. |
Jacobsen, E. N.; Francis, M. B.; Finney, N. S. Combinatorial Approach for Generating Novel Coordination Complexes. U.S. Patent #6489093, December 3, 2002. |
121. |
"Highly Enantioselctive Inverse Electron Demand Hetero-Diels–Alder Reactions of α,β-Unsaturated Aldehydes" Gademann, K.; Chavez, D. E.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2002, 41, 3059–3061. [Supporting Information] |
120. |
Jacobsen, E. N.; Schaus, S. E.; Dossetter, A. G.; Jamison, T. F. Asymmetric Cycloaddition Reactions. U.S. Patent #6369223, April 9, 2002. |
119. |
"Catalyst-Controlled Diastereoselective Hetero-Diels–Alder Reactions" Joly, G. D.; Jacobsen, E. N. Org. Lett. 2002, 4, 1795–1798. [Supporting Information] |
118. |
"A Practical Oligomeric (salen)Co Catalyst for Asymmetric Epoxide Ring Opening Reactions" Ready, J. R.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2002, 41, 1374–1377. [Supporting Information] |
117. |
"Asymmetric Catalysis of Hetero-Ene Reactions with Tridentate Schiff Base Chromium(III) Complexes" Ruck, R. T.; Jacobsen, E. N. J. Am. Chem. Soc. 2002, 124, 2882–2883. [Supporting Information] |
116. |
"A Direct Method for the Conversion of Terminal Epoxides into γ-Butanolides" Movassaghi, M.; Jacobsen, E. N. J. Am. Chem. Soc. 2002, 124, 2456–2457. [Supporting Information] |
115. |
"Highly Selective Hydrolytic Kinetic Resolution of Terminal Epoxides Catalyzed by Chiral (salen)Cobalt(III)-Complexes. Practical Synthesis of Enantioenriched Terminal Epoxides and 1,2-Diols" Schaus, S. E.; Brandes, B. D; Larrow, J. F.; Tokunaga, M.; Hansen, K. B.; Gould, A. E.; Furrow, M. E.; Jacobsen, E. N. J. Am. Chem. Soc. 2002, 124, 1307–1315. [Supporting Information] |
114. |
Jacobsen, E. N.; Sigman, M. S. Parallel Combinatorial Approach to the Discovery and Optimization of Catalysts and Uses Thereof. U.S. Patent #6316616, November 13, 2001. |
113. |
"Total Synthesis of (+)-Ambruticin" Liu, P.; Jacobsen, E. N. J. Am. Chem. Soc. 2001, 123, 10772–10773. [Supporting Information] |
112. |
"FR901464: Total Synthesis, Proof of Structure, and Evaluation of Synthetic Analogs" Thompson, C. F.; Jamison, T. F.; Jacobsen, E. N. J. Am. Chem. Soc. 2001, 123, 9974–9983. [Supporting Information 1, Supporting Information 2] |
111. |
"Total Synthesis of Fostriecin (CI-920)" Chavez, D. E.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2001, 40, 3667–3670. [Supporting Information] |
110. |
Jacobsen, E. N.; Tokunaga, M.; Larrow, J. F. Hydrolytic Kinetic Resolution of Cyclic Substrates. U.S. Patent #6262278 B1, July 17, 2001. |
109. |
"Synthetically Useful, Self-Assembling MMO Mimic System for Catalytic Alkene Epoxidation with Aqueous H2O2" White, M. C.; Doyle, A. G.; Jacobsen, E. N. J. Am. Chem. Soc. 2001, 123, 7194–7195. [Supporting Information] |
108. |
"Regioselective Ring Opening of Enantiomerically Enriched Epoxides via Catalysis with Chiral (Salen)Cr(III) Complexes" Brandes, B. D.; Jacobsen, E. N. Synlett 2001, 1013–1015. |
107. |
Jacobsen, E. N.; Schaus, S. E.; Dossetter, A. G.; Jamison, T. F. Asymmetric Cycloaddition Reactions. U.S. Patent #6211370, April 3, 2001. |
106. |
"Highly Active Oligomeric (salen)Co Catalysts for Asymmetric Epoxide Ring Opening Reactions" Ready, J. M.; Jacobsen, E. N. J. Am. Chem. Soc. 2001, 123, 2687–2688. [Supporting Information] |
105. |
"Practical Synthesis of a Soluble Schiff Base Catalyst for the Asymmetric Strecker Reaction" Su, J. T.; Vachal, P.; Jacobsen, E. N. Adv. Synth. Catal. 2001, 343, 197–200. |
104. |
"Practical Considerations in Kinetic Resolution Reactions" Keith, J. M.; Larrow, J. F.; Jacobsen, E. N. Adv. Synth. Catal. 2001, 343, 5–26. |
103. |
"Total Synthesis of FR901464.Convergent Assembly of Chiral Components Prepared by Asymmetric Catalysis" Thompson, C. F.; Jamison, T. F.; Jacobsen, E. N. J. Am. Chem. Soc. 2000, 122, 10482–10483. [Supporting Information] |
102. |
Jacobsen, E. N.; Schaus, S. E. Asymmetric Cycloaddition Reactions. U.S. Patent #6130340, October 10, 2000. |
101. |
"Cooperative Asymmetric Catalysis with Dendrimeric Co(salen) Complexes" Breinbauer, R.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2000, 39, 3604–3607. |
100. |
"Asymmetric Catalysis of Epoxide Ring-Opening Reactions" Jacobsen, E. N. Acc. Chem. Res. 2000, 33, 421–431. |
99. |
"Asymmetric Ring-Opening of Meso-Epoxides with TMSCN Catalyzed by (pybox)Lanthanide Complexes" Schaus, S. E.; Jacobsen, E. N. Org. Lett. 2000, 2, 1001–1004. [Supporting Information] |
98. |
"Enantioselective Catalytic Addition of HCN to Ketoimines.Catalytic Synthesis of Quaternary Amino Acids" Vachal, P.; Jacobsen, E. N. Org. Lett. 2000, 2, 867–870. [Supporting Information] |
97. |
"A General Catalyst for the Asymmetric Strecker Reaction" Sigman, M. S.; Vachal, P.; Jacobsen, E. N. Angew. Chem., Int. Ed. 2000, 39, 1279–1281. [Supporting Information] |
96. |
"Nickel Comes Full Cycle" Jacobsen, E. N.; Breinbauer, R. Science 2000, 287, 437–438 (Perspective). |
95. |
"Enantioselective Ring-opening of meso Aziridines Catalyzed by Tridentate Schiff-base Chromium(III) Complexes" Li, Z.; Fernandez, M.; Jacobsen, E. N. Org. Lett. 1999, 1, 1611–1613. [Supporting Information] |
94. |
"Enantioselective Parallel Synthesis Using Polymer-Supported Chiral Co(Salen) Complexes" Peukert, S.; Jacobsen, E. N. Org. Lett. 1999, 1, 1245–1248. [Supporting Information] |
93. |
Jacobsen, E. N. Future Perspectives in Asymmetric Catalysis. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Chapter 42. |
92. |
Jacobsen, E. N. Aziridination. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Chapter 17. |
91. |
Jacobsen, E. N.; Wu, M. H. Ring Opening of Epoxides and Related Reactions. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Chapter 35. |
90. |
Jacobsen, E. N.; Wu, M. H. Epoxidation of Alkenes Other than Allylic Alcohols. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer: New York, 1999; Chapter 18.2. |
89. |
"Asymmetric Synthesis of β-Amino Acid Derivatives via Catalytic Conjugate Addition of Hydrazoic Acid to Unsaturated Imides" Myers, J. K.; Jacobsen, E. N. J. Am. Chem. Soc. 1999, 121, 8959–8960. [Supporting Information] |
88. |
"Chromium Catalyzed Kinetic Resolution of 2,2-Disubstituted Epoxides" Lebel, H.; Jacobsen, E. N. Tetrahedron Lett. 1999, 40, 7303–7306. |
87. |
"Highly Enantio- and Diastereoselective Hetero-Diels–Alder Reactions Catalyzed by New Chiral Tridentate Chromium Catalysts" Dossetter, A. G.; Jamison, T. F.; Jacobsen, E. N. Angew. Chem., Int. Ed. 1999, 38, 2398–2400. |
86. |
Jacobsen, E. N.; Martinez, L. E.; Leighton, J. L. Stereoselective Ring Opening Reactions. U.S. Patent #5929232, July 27, 1999. |
85. |
"Regio- and Enantioselective Cyclization of Epoxy Alcohols Catalyzed by a [CoIII(salen)] Complex" Wu, M. H.; Hansen, K. B.; Jacobsen, E. N. Angew. Chem., Int. Ed. 1999, 38, 2012–2014. |
84. |
"Asymmetric Catalytic Synthesis of α-Aryloxy Alcohols: Kinetic Resolution of Terminal Epoxides via Highly Enantioselective Ring Opening with Phenols" Ready, J. M.; Jacobsen, E. N. J. Am. Chem. Soc. 1999, 121, 6086–6087. [Supporting Information 1, Supporting Information 2] |
83. |
Senanayake, C. H.; Jacobsen, E. N. Chiral (Salen)Mn(III) Complexes in Asymmetric Epoxidations: Practical Synthesis of cis-Aminoindanol and Its Application to Enantiopure Drug Synthesis. In Process Chemistry in the Pharmaceutical Industry; Gadamasetti, K. G., Ed.; Dekker: New York, 1999; pp. 347–368. |
82. |
"Polymer-Supported Chiral Co(Salen) Complexes: Synthetic Applications and Mechanistic Investigations in the Hydrolytic Kinetic Resolution of Terminal Epoxides" Annis, D. A.; Jacobsen, E. N. J. Am. Chem. Soc. 1999, 121, 4147–4154. |
81. |
"Discovery of Novel Catalysts for Alkene Epoxidation Using Metal-Binding Combinatorial Libraries" Francis, M. B.; Jacobsen, E. N. Angew. Chem., Int. Ed. 1999, 38, 937–941. |
80. |
"Regioselective Carbomethoxylation of Chiral Epoxides: a New Route to Enantiomerically Pure β-Hydroxyesters" Hinterding, K.; Jacobsen, E.N. J. Org. Chem. 1999, 64, 2164–2165. [Supporting Information] |
79. |
"(1S,2R)-1-Aminoindan-2-ol" Larrow, J. F.; Roberts, E.; Verhoeven, T. R.; Ryan, K. M.; Senanayake, C. H.; Reider, P. J.; Jacobsen, E. N. Org. Synth. 1998, 76, 46–56. |
78. |
"Enantioselective Total Synthesis of Taurospongin A" Lebel, H.; Jacobsen, E. N. J. Org. Chem. 1998, 63, 9624–9625. [Supporting Information 1, Supporting Information 2] |
77. |
"Carbenoid Insertions into the Silicon-Hydrogen Bond Catalyzed by Chiral Copper (I) Schiff Base Complexes" Dakin, L. A.; Schaus, S. E.; Jacobsen, E. N.; Panek, J. S. Tetrahedron Lett. 1998, 39, 8947–8950. |
76. |
"Cooperative Asymmetric Catalysis Using Dimeric Salen Complexes" Konsler, R. G.; Karl, J.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 10780–10781. [Supporting Information] |
75. |
"Practical Access to Highly Enantioenriched C-3 Building Blocks via Hydrolytic Kinetic Resolution" Furrow, M. E.; Schaus, S. E.; Jacobsen, E. N. J. Org. Chem. 1998, 63, 6776–6777. [Supporting Information] |
74. |
"Solid Phase Synthesis of Cyclic RGD Peptide Derivatives via Asymmetric Catalysis: Stereochemistry as a Diversity Element" Annis, D. A.; Jacobsen, E. N. Angew. Chem., Int. Ed. 1998, 37, 1907–1909. |
73. |
"Asymmetric Ring Opening of Meso Epoxides with Thiols: Enantiomeric Enrichment Using a Bifunctional Nucleophile" Wu, M. H.; Jacobsen, E. N. J. Org. Chem. 1998, 63, 5252–5254. [Supporting Information] |
72. |
"Total Synthesis of Muconin by Efficient Assembly of Chiral Building Blocks" Schaus, S. E.; Brånalt, J. E.; Jacobsen, E. N. J. Org. Chem. 1998, 63, 4876–4877. [Supporting Information 1, Supporting Information 2] |
71. |
"Combinatorial Libraries of Transition Metal Complexes, Catalysts, and Materials" Francis, M. B.; Jamison, T. F.; Jacobsen, E. N. Curr. Opin. Chem. Biol. 1998, 2, 422–428. |
70. |
"Enantioselective Addition of Hydrogen Cyanide to Imines Catalyzed by a Chiral (salen)Al(III) Complex" Sigman, M. S.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 5315–5316. [Supporting Information] |
69. |
"Schiff Base Catalysts for the Asymmetric Strecker Reaction Identified and Optimized from Parallel Synthetic Libraries" Sigman, M. S.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 4901–4902. [Supporting Information] |
68. |
"The Mechanistic Basis for Electronic Effects on Enantioselectivity in the (salen)Mn-Catalyzed Epoxidation Reaction” Palucki, M.; Finney, N. S.; Pospisil, P. J.; Güler, M. L.; Ishida, T.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 948–954. [Supporting Information] |
67. |
"Asymmetric Hetero-Diels–Alder Reactions Catalyzed by Chiral (salen)Chromium(III) Complexes" Schaus, S. E.; Brånalt, J. E.; Jacobsen, E. N. J. Org. Chem. 1998, 63, 403–405. [Supporting Information] |
66. |
"(R,R)-N,N'-Bis(3,5-Di-tert-butylsalicylidene)-1,2- Cyclohexanediaminomanganese (III) Chloride, a Highly Enantioselective Epoxidation Catalyst" Larrow, J. F.; Jacobsen, E. N. Org. Synth. 1997, 75, 1–10. |
65. |
"Synthesis of Enantiopure 3-Chlorostyrene Oxide via an Asymmetric Epoxidation/Hydrolytic Kinetic Resolution Sequence" Brandes, B. D.; Jacobsen, E. N. Tetrahedron: Asymm. 1997, 8, 3927–3933. |
64. |
Jacobsen, E. N.; Martinez, L. E.; Leighton, J. L. Stereoselective Ring Opening Reactions. U.S. Patent #5665890, September 9, 1997. |
63. |
"On the Viability of Metallaoxetane Intermediates in the (salen)Mn-Catalyzed Asymmetric Epoxidation Reaction" Finney, N. S.; Pospisil, P. J.; Chang, S.; Palucki, M.; Hansen, K. B.; Jacobsen, E. N. Angew. Chem. Int. Ed. Engl. 1997, 36, 1720–1723. |
62. |
"Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by Means of Catalytic Hydrolysis" Tokunaga, M.; Larrow, J. F.; Kakiuchi, F.; Jacobsen, E. N. Science 1997, 277, 936–938. |
61. |
Jacobsen, E. N.; Zhang, W.; Deng, L. Chiral Catalysts and Epoxidation Reactions. U.S. Patent #5663393, September 2, 1997. |
60. |
Jacobsen, E. N.; Zhang, W.; Deng, L. Chiral Catalysts and Epoxidation Reactions Catalyzed Thereby. U.S. Patent #5637739, June 10, 1997. |
59. |
"Practical Synthesis of Enantiopure Cyclic 1,2-Aminoalcohols via Catalytic Asymmetric Ring Opening of Meso Epoxides" Schaus, S. E.; Larrow, J. F.; Jacobsen, E. N. J. Org. Chem. 1997, 62, 4197–4199. [Supporting Information] |
58. |
"An Efficient Formal Synthesis of Balanol via the Asymmetric Epoxide Ring Opening Reaction" Wu, M. H.; Jacobsen, E. N. Tetrahedron Lett. 1997, 38, 1693–1696. |
57. |
"Enantioselective Catalytic Ring Opening of Epoxides with Carboxylic Acids" Jacobsen, E. N.; Kakiuchi, F.; Konsler, R. G.; Larrow, J. F.; Tokunaga, M. Tetrahedron Lett. 1997, 38, 773–776. |
56. |
"On the Mechanism of Asymmetric Nucleophilic Ring-Opening of Epoxides Catalyzed by (Salen)Cr(III) Complexes" Hansen, K. B.; Leighton, J. L.; Jacobsen, E. N. J. Am. Chem. Soc. 1996, 118, 10924–10925. [Supporting Information] |
55. |
"Dynamic Kinetic Resolution of Epichlorohydrin via Enantioselective Catalytic Ring Opening with TMSN3. Practical Synthesis of Aryl Oxazolidinone Antibacterial Agents" Schaus, S. E.; Jacobsen, E. N. Tetrahedron Lett. 1996, 37, 7937–7940. |
54. |
"Highly Efficient and Enantioselective Synthesis of Carbocyclic Nucleoside Analogs Using Selective Early Transition Metal Catalysis" Martinez, L. E.; Nugent, W. A.; Jacobsen, E. N. J. Org. Chem. 1996, 61, 7963–7966. |
53. |
"Combinatorial Approach to the Discovery of Novel Coordination Compounds" Francis, M. B.; Finney, N. S.; Jacobsen, E. N. J. Am. Chem. Soc. 1996, 118, 8983–8984. [Supporting Information] |
52. |
"Enantioselective Binding of Prochiral Olefins to a Chiral Catalyst via Simultaneous Face-Face and Edge-Face Aromatic Interactions" Quan, R. W.; Li, Z.; Jacobsen, E. N. J. Am. Chem. Soc. 1996, 118, 8156–8157. [Supporting Information] |
51. |
"X-Ray Structural Studies of Highly Enantioselective Mn(salen) Epoxidation Catalysts" Pospisil, P. J.; Carsten, D. H.; Jacobsen, E. N. Chem. Eur. J. 1996, 2, 974–980. |
50. |
"Kinetic Resolution of Terminal Epoxides via Highly Regioselective and Enantioselective Ring Opening with TMSN3. An Efficient, Catalytic Route to 1,2-Aminoalcohols" Larrow, J. F.; Schaus, S. E.; Jacobsen, E. N. J. Am. Chem. Soc. 1996, 118, 7420–7421. [Supporting Information] |
49. |
"Efficient Synthesis of (R)-4-Trimethylsilyloxy-2- cyclopentenone by Enantioselective Catalytic Epoxide Ring Opening" Leighton, J. L.; Jacobsen, E. N. J. Org. Chem. 1996, 61, 389–390. [Supporting Information] |
48. |
"Kinetic Resolution of Racemic Chromenes via Asymmetric Epoxidation; Synthesis of (+)-Teretifolione B" Vander Velde, S. L.; Jacobsen, E. N. J. Org. Chem. 1995, 60, 5380–5381. [Supporting Information 1, Supporting Information 2] |
47. |
"Low Temperature Asymmetric Epoxidation of Unfunctionalized Olefins Catalyzed by (salen)Mn(III) Complexes" Palucki, M.; McCormick, G. J.; Jacobsen, E. N. Tetrahedron Lett. 1995, 36, 5457–5460. |
46. |
"Enantioselective Catalytic Epoxidation of Tetrasubstituted Olefins" Brandes, B. D.; Jacobsen, E. N. Tetrahedron Lett. 1995, 36, 5123–5126. |
45. |
Jacobsen, E. N. Fundamental and Applied Studies in Asymmetric Oxidation Catalysis. In Stereoselective Reactions of Metal-Activated Molecules; Werner, H., Sundmeyer, J., Eds.; Vieweg: New York, 1995; pp. 17–26. |
44. |
Jacobsen, E. N. Transition Metal Catalyzed Oxidations: Asymmetric Epoxidation. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G. A., Abel, E. W., Hegedus, L. S., Eds.; Pergamon: New York, 1995; Volume 12; pp. 1097–1135. |
43. |
"Mechanistic Study of the (diimine)Cu-Catalyzed Asymmetric Azridination of Alkenes. Nitrene Transfer via Ligand-Accelerated Catalysis" Li, Z.; Quan, R. W.; Jacobsen, E. N. J. Am. Chem. Soc. 1995, 117, 5889–5890. [Supporting Information] |
42. |
"Highly Enantioselective Ring Opening of Epoxides Catalyzed by Chiral (salen)Cr(III) Complexes" Martínez, L. E.; Leighton, J. L.; Carsten, D. H.; Jacobsen, E. N. J. Am. Chem. Soc. 1995, 117, 5897–5898. [Supporting Information] |
41. |
Jacobsen, E. N. Sodium Hypochlorite-Chiral Manganese (III) Salen Complexes. In Encyclopedia of Reagents for Organic Synthesis; Paquette, L. A., Ed.; Wiley: New York, 1995; Volume 7; pp. 4585–4586. |
40. |
Jacobsen, E. N.; Galvin, J. M. Sodium Hypochlorite. In Encyclopedia of Reagents for Organic Synthesis; Paquette, L.A., Ed.; Wiley: New York, 1995; Volume 7; pp. 4580–4585. |
39. |
"Carbenoid Transfer to Imines: A New Asymmetric Catalytic Synthesis of Aziridines" Hansen, K. H.; Finney, N. S.; Jacobsen, E. N. Angew. Chem. Int. Ed. Engl. 1995, 34, 676–678. |
38. |
"Synthetic and Biological Catalysts for Chemical Synthesis: How to Assess Practical Utility" Jacobsen, E. N.; Finney, N. S. Chem. Biol. 1994, 1, 85–90. |
37. |
"Kinetic Resolution of 1,2-Dihydronaphthalene Oxide and Related Epoxides via Asymmetric C–H Hydroxylation" Larrow, J. F.; Jacobsen, E. N. J. Am. Chem. Soc. 1994, 116, 12129–12130. |
36. |
"Highly Enantioselective, Low Temperature Epoxidation of Terminal Olefins" Palucki, M.; Pospisil, P. J.; Zhang, W.; Jacobsen, E. N. J. Am. Chem. Soc. 1994, 116, 9333–9334. [Supporting Information] |
35. |
"Highly Enantioselective, Catalytic Epoxidation of Trisubstituted Olefins" Brandes, B. D.; Jacobsen, E. N. J. Org. Chem. 1994, 59, 4378–4380. [Supporting Information] |
34. |
"Effect of Chiral Quaternary Ammonium Salts on (salen)Mn-Catalyzed Epoxidation of cis-Olefins. A Highly Enantioselective, Catalytic Route to Trans Epoxides" Chang, S.; Galvin, J. M.; Jacobsen, E. N. J. Am. Chem. Soc. 1994, 116, 6937–6938. [Supporting Information] |
33. |
"A Practical Process for the Large-Scale Preparation of (R,R)-N,N'-Bis(3,5-Di-tert-butylsalicylidene)-1,2-Cyclohexanediaminomanganese (III) Chloride, a Highly Enantioselective Epoxidation Catalyst" Larrow, J. F.; Jacobsen, E. N.; Gao, Y.; Hong, Y.; Nie, X.; Zepp, C. M. J. Org. Chem. 1994, 59, 1939–1940. [Supporting Information] |
32. |
"Enantioselective Epoxidation of Cyclic 1,3-Dienes Catalyzed by a Sterically and Electronically Optimized (Salen)Mn Complex" Chang, S.; Heid, R. M.; Jacobsen, E. N. Tetrahedron Lett. 1994, 35, 669–672. |
31. |
"Enantioselective Catalytic Epoxidation of Cinnamate Esters" Jacobsen, E. N.; Deng, L.; Furukawa, Y.; Martínez, L. E. Tetrahedron 1994, 50, 4323–4334. |
30. |
"Non-Stereospecific Mechanisms in Asymmetric Addition to Alkenes Result in Enantiodifferentiation after the First Irreversible Step" Zhang, W.; Lee, N. H.; Jacobsen, E. N. J. Am. Chem. Soc. 1994, 116, 425–426. [Supporting Information] |
29. |
"Regio- and Enantioselective Epoxidation of Conjugated Polyenes. Formal Synthesis of LTA4 Methyl Ester" Chang, S.; Lee, N. H.; Jacobsen, E. N. J. Org. Chem. 1993, 58, 6939–6941. [Supporting Information] |
28. |
"Synthesis and Characterization of Chiral Bimetallic Complexes Bearing Hard and Soft Lewis Acidic Sites" Fields, L. B.; Jacobsen, E. N. Tetrahedron: Asymm. 1993, 4, 2229–2240. |
27. |
Jacobsen, E. N. Asymmetric Catalytic Epoxidation of Unfunctionalized Olefins. In Catalytic Asymmetric Synthesis; Ojima, I., Ed.; VCH: New York, 1993; Chapter 4.2. |
26. |
"Encouraging Tomorrow's Chemists: University Outreach Program Bringing Hands-On Experiments to Local Students" Heinze, K. F.; Allen, J. L.; Jacobsen, E. N. J. Chem. Ed. 1995, 72, 167–169. |
25. |
"Highly Enantioselective Epoxidation of Disubstituted Alkenes with Hydrogen Peroxide Catalyzed by Chloroperoxidase" Allain, E. A.; Hager, L. P.; Deng, L.; Jacobsen, E. N. J. Am. Chem. Soc. 1993, 115, 4415–4416. [Supporting Information] |
24. |
"Asymmetric Alkene Aziridination with Readily Available Chiral Diimine-Based Catalysts" Li, Z.; Conser, K. R.; Jacobsen, E. N. J. Am. Chem. Soc. 1993, 115, 5326–5327. [Supporting Information] |
23. |
"Salen-Manganese Complexes are Superoxide Dismutate Mimics" Baudry, M.; Etienne, S.; Bruce, A.; Palucki, M.; Jacobsen, E.; Malfroy, B. Biochem. Biophys. Res. Commun. 1993, 192, 964–968. |
22. |
"Asymmetric Oxidation of Sulfides with H2O2-Catalyzed by (salen)Mn(III) Complexes" Palucki, M.; Hanson, P.; Jacobsen, E. N. Tetrahedron Lett. 1992, 33, 7111–7114. |
21. |
"A Substoichiometric Pyridine•Lithium Enolate Complex: Solution and X-Ray Data, and Implications to Catalysis in the Aldol Reaction" Pospisil, P. J.; Jacobsen, E. N. J. Am. Chem. Soc. 1992, 114, 7585–7587. [Supporting Information] |
20. |
"A Practical, Highly Enantioselective Synthesis of the Taxol Side Chain via Asymmetric Catalysis" Deng, L.; Jacobsen, E. N. J. Org. Chem. 1992, 57, 4320–4323. |
19. |
"Enantioselective Epoxidation of Conjugated Dienes and Enynes. Trans-Epoxides from Cis-Olefins" Lee, N. H.; Jacobsen, E. N. Tetrahedron Lett. 1991, 32, 6533–6536. |
18. |
"Enantiomerically Pure Epoxychromans via Asymmetric Catalysis" Lee, N. H.; Muci, A. R.; Jacobsen, E. N. Tetrahedron Lett. 1991, 32, 5055–5058. |
17. |
Jacobsen, E. N. Asymmetric Synthesis. In 1992 Yearbook of Science & Technology; McGraw-Hill, Inc.: New York, 1991; p 34. |
16. |
"Electronic Tuning of Asymmetric Catalysts" Jacobsen, E. N.; Güler, M. L.; Zhang, W. J. Am. Chem. Soc. 1991, 113, 6703–6704. |
15. |
"Mechanistic Study of a Synthetically Useful Mono-oxygenase Model Using Hypersensitive Probes cis and trans-2-phenyl-1-Vinylcyclopropane" Fu, H.; Look, G. C.; Zhang, W.; Jacobsen, E. N.; Wong, C.-H. J. Org. Chem. 1991, 56, 6497–6500. [Supporting Information] |
14. |
"Highly Enantioselective Epoxidation Catalysts Derived from 1,2-Diaminocyclohexane" Jacobsen, E. N.; Zhang, W.; Muci, A. R.; Ecker, J. R.; Deng, L. J. Am. Chem. Soc. 1991, 113, 7063–7064. [Supporting Information] |
13. |
"Asymmetric Epoxidation with Sodium Hypochlorite Catalyzed by Readily Available Chiral Mn(III) Salen Complexes" Zhang, W.; Jacobsen, E. N. J. Org. Chem. 1991, 56, 2296–2298. [Supporting Information] |
12. |
"Preparation of trans-1,2-Diamino-1,2-Dimethylcyclohexane via Highly Stereoselective Olefin Oxidation by Dinitrogen Tetroxide" Zhang, W.; Jacobsen, E. N. Tetrahedron Lett. 1991, 32, 1711–1714. |
11. |
"Enantioselective Epoxidation of Unfunctionalized Olefins Catalyzed by (salen)Manganese Complexes" Zhang, W.; Loebach, J. L.; Wilson, S. R.; Jacobsen, E. N. J. Am. Chem. Soc. 1990, 112, 2801–2803. |
10. |
"On the Structure of Osmium Tetroxide-Cinchona Alkaloid Complexes" Svendsen, J. S.; Markó, I. E.; Jacobsen, E. N.; Pulla Rao, Ch.; Bott, S.; Sharpless, K. B. J. Org. Chem. 1989, 54, 2263. |
9. |
"A Mechanistic Insight Leads to a Greatly Improved Osmium-Catalyzed Asymmetric Dihydroxylation Process" Wai, J. S. M.; Markó, I. E.; Svendsen, J. S.; Finn, M. G.; Jacobsen, E. N.; Sharpless, K. B. J. Am. Chem. Soc. 1989, 111, 1123. |
8. |
"Kinetic Role of Alkaloid Ligands in Asymmetric Catalytic Dihydroxylation" Jacobsen, E. N.; Markó, I. E.; France, M. B.; Svendsen, J. S.; Sharpless, K. B. J. Am. Chem. Soc. 1989, 111, 737. |
7. |
"Rapid, Reversible Intramolecular C–H Oxidative Addition and H-Exchange in a Heterodinuclear 'Early-Late' Transition Metal Complex" Jacobsen, E. N.; Goldberg, K. I.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 3706. |
6. |
"Asymmetric Dihydroxylation via Ligand-Accelerated Catalysis" Jacobsen, E. N.; Markó, I. E.; Mungall, W. S.; Schröder, G. W.; Sharpless, K. B. J. Am. Chem. Soc. 1988, 110, 1968. |
5. |
"Synthesis of Organometallic Heterodinuclear µ-Oxo Complexes by Extrusion of Alkenes from Zirconium/Tungsten Oxaalkyl Complexes" Jacobsen, E. N.; Trost, M. K.; Bergman, R. G. J. Am. Chem. Soc. 1986, 108, 8092. |
4. |
"Synthesis and Chemistry of a Bridging Vinylidenedicobalt Complex. Evidence for a Non-Chain Radical Mechanism in its Reaction with Metal Hydrides to Give Heteronuclear Clusters" Jacobsen, E. N.; Bergman, R. G. J. Am. Chem. Soc. 1985, 107, 2023. |
3. |
"Steric Effects on the Titanium Tetrachloride-Promoted Dimerization of Silyl Ketene Acetals" Jacobsen, E. N.; Totten, G. E.; Wenke, G.; Karydas, A. C.; Rhodes, Y. E. Synth. Commun. 1985, 15, 301. |
2. |
"Synthesis, Crystal and Molecular Structure, and Reactions of the Bridging Vinylidenedicobalt Complex (µ-CCH2)(CpCoCO)2. Reaction with Molybdenum Hydrides to Give a Heteronuclear Cluster Complex" Jacobsen, E. N.; Bergman, R. G. Organometallics 1984, 3, 329. |
1. |
"Silyl Ketene Acetal Chemistry: Steric Limitations in Lewis Acid-Promoted Addition of Ketones" Wenke, G.; Jacobsen, E. N.; Totten, G. E.; Karydas, A. C.; Rhodes, Y. E. Synth. Commun. 1983, 13, 449. |